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Are you upsetting the car and braking hard once in the turn/lift off oversteer or were you already at 30mph, keeping the car at a constant speed through the turn and still getting the back end to come out? Sounds like you then over-corrected and that caused the car to go back the other way. Have you had any rear end damage? Maybe even a pothole that could have messed up the rear geometry? Something like that could cause this effect to be more dramatic. Or if it had just started raining, could be just a higher chance of slick road surface and a fluke too.
As Billfitz said, i have tried to upset the car to have some fun and cant get the car to do what you are seeing. Again, xdrive here and underpowered 328, so not able to fully power into things, less tq than your 335d too.
The non-runflats will help with feel and the Pilots will definitely handle better than your current rft. I would suggest getting the alignment looked at as well though, just to know its not that.
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